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Genes Dev 2014

As a result of this strong orbital mixing and electron transfer during the CASSCF(14,13) geometric optimization, the Co-C and Co-O bond lengths in cyanocobalamin, methylcobalamin, and aquacobalamin increase steadily until they entirely break at the end of the optimization process

Also, it is a key enzyme involved in one of the central pathways of one-carbon metabolism and is essential for various cellular functions, including DNA synthesis, methylation reactions, and the production of important molecules such as SAM

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A decrease in this ratio indicates increased oxidative stress, potentially triggering stress response programs such as apoptosis, necrosis, or autophagy